QUOTE (BobLfoot @ Sep 25 2009, 11:25 PM)

Phase Current passing through ground most likely tripped the MCC Breaker
OK, so you suspect line-ground fault. I concur based on your description. Based on the force involved it also sounds like you've got a solid-grounded delta-wye system. For future reference you may want to consider a high resistance ground. I think NEC now sort of pushes you in that direction for anything over 1000 A anyways which it sounds like you are either at or close to. They are not really that complicated to deal with and have the advantage that line-ground faults do not exceed 25-50 A. The downside is that you have to add an extra protective relay or two, and a resistor. But the cost isn't that much compared to what you typically see with MCC/MVC gear overall.
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I would suspect a couple of possibles. Loss of Phase Trip and Ground Current Trip
Loss of phase with a motor circuit (I'm assuming motor circuit here...correct me if I'm wrong) implies that the motor will then start returning energy through the missing phase leg, "single phasing". Current in this leg temporarily increases to roughly twice normal (actually 1.73 times) until the overload trips it out. Instantaneous trips usually need not apply in this case.
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Sub Breakers Calibrated in July 09 when installed
MCC Breaker new from Manufacturer installed 9/19 with Cal Sheet
Whoa...OK, that's also important to know. It is definitely POSSIBLE that the breakers were off but doubtful. If you bought new, I hope you bought electronic trip units because they are much more reliable and generally speaking, calibration is simply not a factor. The various heating/temperature problems go away, too. Based on the size you bought, I'd default to vaccuum circuit breakers too because they will be smaller and immune to those things that shouldn't be inside the compartment (dust). Circuit breaker life is longer too...usually the limiting factor on life shifts from the contact tips to the mechanical components.
There is still clearly a coordination problem here so you really should be looking really closely at your coordination curves and getting this straightened out. If this is after the fact and you find you have a very difficult coordination problem and can't live with it (sounds like this is one of them), you can contact Utility Relay Company (they have a web site) and buy a rebuild kit for about $2500-$3500 for low voltage draw out circuit breakers. This rebuild kit will convert existing draw-out circuit breakers from mechanical to electronic trip units and also includes all the parts to rebuild/overhaul old units. If it's a molded case type, then your only choice will be replacement. Check out the electronic circuit breakers, often with current limiting functions, available from all the major manufacturers. They are surprisingly inexpensive, often cheaper than the old standard thermal/magnetic types at the sizes you are looking at. If it's a medium voltage unit with a separate protective relay, then just buy an upgraded relay. Often they will fit right in the exact same slot as the old relay. These newer relays add LOTS of new settings and you can trivially tune your coordination curves to avoid just about any kind of coordination problem with the possible exception of the notorious problems with mixed fuses and circuit breakers (hard to match a circuit breaker to a fuse curve and vice versa).
An additional advantage is that you can probably drop your arc flash ratings down to near 1. If you really want to do something about that in particular, check out VAMP or ABB. Both sell after-market fiber optic trip units that can be retrofitted onto existing switch gear to protect your high power buses. The result is often that you can take even a hazard class 4 unit down to 0 or 1. They are relatively inexpensive (<$10K) because it consists of just an unclad fiber that you fish through all the compartments, a sensing relay, a second low burden relay that you connect to one of your CT's on the front end, and a trigger relay to trip the main CB when an arc flash event occurs, all in under 10 ms. The limiting factor on speed turns into the speed that your primary CB can open (2 to 5 cycles), not the speed of the "instantaneous" trip units.
Since you've only had roughly 2 months of run life, my biggest suspicion is installation error on cable pulling. With 500 MCM cable, if you don't make sure to put in the proper number of pulling boxes, debur every single conduit, cut with the proper threading head (NSPT, not the more common NPT), put plastic bushings on the exposed threaded ends, use a proper pulling eye, and liberally use lots and lots of cable pulling compound, your chances of nicking or stretching/damaging a cable go way up. There's a right way to pull 500 MCM conductors which can be done without causing mechanical damage. Done right, you will never have a failure like what you described. I usually don't spend a lot of time hanging around the site when cable pulling is being done because there's really not much to see. But for the large conductors and for proper terminations on 5kV and higher cabling, I don't make a big show of it but this is one time to spend ALL your time on the site monitoring the activities. 5kV and higher cable is supposed to be insulation tested (hi pot) specifically to detect any problems such as this. I'd suggest you consider hi pot testing it now while it's down in case you find another one. I'm a very anti-hi pot guy except on new installations and this is probably close enough to be considered new. If the cable wasn't so new then I'd recommend meggering it which at least isn't a potentially destructive test. I'd let the installation crew know just how disappointed I am too but since there's no way at this point to detect where/when the screw up occurred and you didn't test the cabling, it is impossible to go after them contractually.
Note that I only recommend hi pot testing on NEW cable when installed. If you attempt to hi pot test once cable has been in service more than likely it will test bad. AND worse yet, hi pot testing on used equipment actually CAUSES insulation damage, becoming a self-fulfilling prophecy. Also, hi pot testing on transformer bushings tends to be very vague on results and often "fails" on medium voltage transformer bushings, so you sort of have to "interpret" the readings a bit. The hi pot testing literature is rife with descriptions of this.