Problem has been solved!! Very interesting findings.... The TSX ETY - 410 ethernet card on the premium PLC configuration has the option to use either Ethernet II or IEEE 802.3 as the protocol. It seems that Ethernet II is the newer of the two. The Ety Ethernet card was configured to use IEEE 802.3. This results in the format of the ARP responce being different and it seems that the 1769-L24 compactlogix ethernet card does not support IEEE 802.3. I changed the protocol on th ETY card to use Ethernet II. Now the CompactLogix recognises the ARP responce and the connection works! It's been a while since I had to do so mutch Wireshark low level digging! Thanks and I hope this helps some other poor sod in the future.